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就共价有机框架(COFs)及其复合材料在有机和无机污染物吸附中的应用进行综述.COFs作为吸附剂的研究重点在于选择合适的构筑单元和制备功能化的COFs以用于吸附不同的污染物.COFs吸附污染物时,表现出吸附容量大、吸附速率快、稳定性强、重复性好等优点.此外,将COFs分别与离子液体(ILs)、纳米粒子或机械载体等材料复合可制备基于COFs的复合材料,从而赋予其操作性和机械性能,便于实际应用.最后,对COFs作为吸附剂在水处理领域的研究进行了展望.
Abstract：Covalent organic frameworks(COFs)containing composite materials in the adsorption of organic and inorganic compounds have been reviewed. The research of COFs used as adsorbents is now focused on the selection of appropriate construction units and the development of functionalized COFs for the adsorption of different pollutants. COFs as adsorbents have the advantages of high adsorption capacity,fast adsorption rate,good stability and repeatability. In addition,composite materials of COFs prepared by combining COFs with ionic liquids(ILs),nanoparticles,and mechanical support,respectively,have additional maneuverability and mechanical properties,which can promote their practical application capacity. Prospects for future research in the field of water treatment have been proposed.
[1] Lu Y,Song S,Wang R,et al. Impacts of soil and water pollution on food safety and health risks in China[J].Environment International,2015,77:5-15.
[2] Ebele A J,Abou-Elwafa Abdallah M,Harrad S. Pharmaceuticals and personal care products(PPCPs)in the freshwater aquatic environment[J]. Emerging Contaminants,2017,3(1):1-16.
[3] Gogoi A,Mazumder P,Tyagi V K,et al. Occurrence and fate of emerging contaminants in water environment:A review[J]. Groundwater for Sustainable Development,2018,6:169-180.
[4]陈文华，李刚，许方程，等.染料废水污染现状及处理方法研究进展[J].浙江农业科学，2014(2):264-269.
[5]焦海林.关于水体重金属污染现状分析及其健康风险评价[J].化工管理，2019(21):47-48.
[6]梁晓军，宋文磊，李建，等.饮用水放射性污染现状及健康风险评价研究进展[J].职业与健康，2015,31(3):417-419.
[7]王未，黄从建，张满成，等.我国区域性水体农药污染现状研究分析[J].环境保护科学，2013,39(5):5-9.
[8] Mohan D,Sarswat A,Ok Y S,et al. Organic and inorganic contaminants removal from water with biochar,a renewable,low cost and sustainable adsorbent:A critical review[J]. Bioresource Technology,2014,160:191-202.
[9] Xiang Z,Cao D. Porous covalent-organic materials:Synthesis,clean energy application and design[J]. Journal of Materials Chemistry A,2013,1(8):2691-2718.
[10] Cote A P,Benin A I,Ockwig N W,et al. Porous,crystalline,covalent organic frameworks[J]. Science,2005,310(5751):1166-1170.
[11]王帅.共价有机框架(COFs)材料最新应用研究进展[J].江西化工，2018(2):1-3.
[12] Ding S Y,Wang W. Covalent organic frameworks(COFs):From design to applications[J]. Chemical Society Reviews,2013,42(2):548-568.
[13] Feng X,Ding X,Jiang D. Covalent organic frameworks[J]. Chemical Society Reviews,2012,41(18):6010-6022.
[14]刘建华，葛春华，张向东，等.基于有机硼酸的共价键有机框架研究进展[J].化学通报，2012,75(5):432-440.
[15]刘春晖，马晓莉.共价有机框架材料的最新进展[J].化工进展，2019,38(11):4978-4990.
[16] Kandambeth S,Mallick A,Lukose B,et al. Construction of crystalline 2D covalent organic frameworks with remarkable chemical(acid/base)stability via a combined reversible and irreversible route[J]. Journal of the American Chemical Society,2012,134(48):19524-19527.
[17] Dinari M,Hatami M. Novel N-riched crystalline covalent organic framework as a highly porous adsorbent for effective cadmium removal[J]. Journal of Environmental Chemical Engineering,2019,7(1):102907.
[18] Ghazi Z A,Khattak A M,Iqbal R,et al. Adsorptive removal of Cd2+from aqueous solutions by a highly stable covalent triazine-based framework[J]. New Journal of Chemistry,2018,42(12):10234-10242.
[19] Ding S Y,Dong M,Wang Y W,et al. Thioether-based fluorescent covalent organic framework for selective detection and facile removal of mercury(Ⅱ)[J]. Journal of the American Chemical Society,2016,138(9):3031-3037.
[20] Zhou Z,Zhong W,Cui K,et al. A covalent organic framework bearing thioether pendant arms for selective detection and recovery of Au from ultra-low concentration aqueous solution[J]. Chemical Communications,2018,54(71):9977-9980.
[21] Huang N,Zhai L,Xu H,et al. Stable covalent organic frameworks for exceptional mercury removal from aqueous solutions[J]. Journal of the American Chemical Society,2017,139(6):2428-2434.
[22] Li G,Ye J,Fang Q,et al. Amide-based covalent organic frameworks materials for efficient and recyclable removal of heavy metal lead(Ⅱ)[J]. Chemical Engineering Journal,2019,370(15):822-830.
[23] Merí-BofíL,Royuela S,Zamora F,et al. Thiol grafted imine-based covalent organic frameworks for water remediation through selective removal of Hg(Ⅱ)[J].Journal of Materials Chemistry A,2017,5(34):17973-17981.
[24] Jiang Y,Liu C,Huang A,et al. EDTA-functionalized covalent organic framework for the removal of heavymetal ions[J]. ACS Applied Materials Interfaces,2019,11(35):32186-32191.
[25] Lu Q,Ma Y,Li H,et al. Postsynthetic functionalization of three-dimensional covalent organic frameworks for selective extraction of lanthanide ions[J]. Angewandte Chemie International Edition,2018,57(21):6042-6048.
[26] Cui F,Liang R,Qi Q,et al. Efficient removal of Cr(VI)from aqueous solutions by a dual-pore covalent organic framework[J]. Advanced Sustainable Systems,2019,3(4):1800150.
[27] Li Z D,Zhang H Q,Xiong X H,et al. U(VI)adsorption onto covalent organic frameworks-TpPa-1[J]. Journal of Solid State Chemistry,2019,277:484-492.
[28] Sun Q,Aguila B,Earl L D,et al. Covalent organic frameworks as a decorating platform for utilization and affinity enhancement of chelating sites for radionuclide sequestration[J]. Advanced Materials,2018,30(20):1705479.
[29] Li J,Yang X,Bai C,et al. A novel benzimidazolefunctionalized 2-D COF material:Synthesis and application as a selective solid-phase extractant for separation of uranium[J]. Journal of Colloid and Interface Science,2015,437:211-218.
[30] Xiong X H,Yu Z W,Gong L L,et al. Ammoniating covalent organic framework(COF)for high-performance and selective extraction of toxic and radioactive uranium ions[J]. Advanced Science,2019,6(16):1900547.
[31] Zhuang S,Liu Y,Wang J J. Covalent organic frameworks as efficient adsorbent for sulfamerazine removal from aqueous solution[J]. Journal of Hazardous Materials,2020,383:121126.
[32] Salonen L M,Pinela S R,Fernandes S P S,et al. Adsorption of marine phycotoxin okadaic acid on a covalent organic framework[J]. Journal of Chromatography A,2017,1525:17-22.
[33] Mellah A,Fernandes S P S,Rodriguez Z R,et al. Adsorption of pharmaceutical pollutants from water using covalent organic frameworks[J]. Chemistry-A European Journal,2018,24(42):10601-10605.
[34] Liu J,Zong E,Fu H,et al. Adsorption of aromatic compounds on porous covalent triazine-based framework[J].Journal of Colloid and Interface Science,2012,372(1):99-107.
[35] Liao Q,Ke C,Huang X,et al. Catalyst-free and efficient fabrication of highly crystalline fluorinated covalent organic frameworks for selective guest adsorption[J].Journal of Materials Chemistry A,2019,7(32):18959-18970.
[36] Li Y,Chen W,Hao W,et al. Covalent organic frameworks constructed from flexible building blocks with high adsorption capacity for pollutants[J]. ACS Applied Nano Materials,2018,1(9):4756-4761.
[37] Wang R Q,Wei X B,Feng Y Q.β-Cyclodextrin covalent organic framework for selective molecular adsorption[J].Chemistry-A European Journal,2018,24(43):10979-10983.
[38] Ji W,Xiao L,Ling Y,et al. Removal of gen X and perfluorinated alkyl substances from water by aminefunctionalized covalent organic frameworks[J]. Journal of the American Chemical Society,2018,140(40):12677-12681.
[39] Kandambeth S,Biswal B P,Chaudhari H D,et al. Selective molecular sieving in self-standing porous covalentorganic-framework membranes[J]. Advanced Materails,2017,29(2):201603945.
[40] Yu S B,Lyu H,Tian J,et al. A polycationic covalent organic framework:A robust adsorbent for anionic dye pollutants[J]. Polymer Chemistry,2016,7(20):3392-3397.
[41] Huang N,Wang P,Addicoat M A,et al. Ionic covalent organic frameworks:Design of a charged interface aligned on 1D channel walls and its unusual electrostatic functions[J]. Angewandte Chemie International Edition,2017,56(18):4982-4986.
[42] Li Z,Li H,Guan X,et al. Three-dimensional ionic covalent organic frameworks for rapid,reversible,and selective ion exchange[J]. Journal of the American Chemical Society,2017,139(49):17771-17774.
[43] Leus K,Folens K,Nicomel N R,et al. Removal of arsenic and mercury species from water by covalent triazine framework encapsulatedγ-Fe2O3 nanoparticles[J]. Journal of Hazardous Materials,2018,353:312-319.
[44] Li Y,Yang C,Yan X. Controllable preparation of coreshell magnetic covalent-organic framework nanospheres for efficient adsorption and removal of bisphenols in aqueous solution[J]. Chemical Communications,2017,53(16):2511-2514.
[45] Zhang W,Liang F,Li C,et al. Microwave-enhanced synthesis of magnetic porous covalent triazine-based framework composites for fast separation of organic dye from aqueous solution[J]. Journal of Hazardous Materials,2011,186(2):984-990.
[46] Wen R,Li Y,Zhang M,et al. Graphene-synergized 2D covalent organic framework for adsorption:A mutual promotion strategy to achieve stabilization and functionalization simultaneously[J]. Journal of Hazardous Materials,2018,358:273-285.
[47] Sun Q,Aguila B,Perman J A,et al. Integrating superwettability within covalent organic frameworks for functional coating[J]. Chem,2018,4(7):1726-1739.
[48] Liu Z,Wang H,Ou J,et al. Construction of hierarchically porous monoliths from covalent organic frameworks(COFs)and their application for bisphenol A removal[J]. Journal of Hazardous Materials,2018,355:145-153.
[49] Zhang W,Zhang L,Zhao H,et al. A two-dimensional cationic covalent organic framework membrane for selective molecular sieving[J]. Journal of Materials Chemistry A,2018,6(27):13331-13339.
基本信息:
DOI：10.13364/j.issn.1672-6510.20190295
中图分类号:TB33;X703
引用信息:
[1]方国臻,党梦,田炎炎,等.共价有机框架及其复合材料在水处理中的应用[J].天津科技大学学报,2020,35(04):1-7+13.DOI:10.13364/j.issn.1672-6510.20190295.
基金信息:
国家自然科学基金资助项目(21375094);; 国家重点研发计划资助项目(2016YFD0401101)
2020-08-23
2020-08-23